Thermo-kinetic study to elucidate the bioenergy potential of Maple Leaf Waste (MLW) by pyrolysis, TGA and kinetic modelling

The present study aims to evaluate the feasibility of Maple Leaf Waste (MLW) for the first time to produce biofuel-bioenergy and chemicals. It is meaningful to understand the thermochemical conversion and degradation pattern of the MLW to evaluate its biofuel-bioenergy potential. Different degradati...

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Main Authors: Ahmad, M.S., Klemeš, J.J., Alhumade, H., Elkamel, A., Mahmood, A., Shen, B., Ibrahim, M., Mukhtar, A., Saqib, S., Asif, S., Bokhari, A.
Format: Article
Institution: Universiti Teknologi Petronas
Record Id / ISBN-0: utp-eprints.30360 /
Published: Elsevier Ltd 2021
Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85101636207&doi=10.1016%2fj.fuel.2021.120349&partnerID=40&md5=68ce4582bd33d204f29206815b330492
http://eprints.utp.edu.my/30360/
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spelling utp-eprints.303602022-03-25T06:44:29Z Thermo-kinetic study to elucidate the bioenergy potential of Maple Leaf Waste (MLW) by pyrolysis, TGA and kinetic modelling Ahmad, M.S. Klemeš, J.J. Alhumade, H. Elkamel, A. Mahmood, A. Shen, B. Ibrahim, M. Mukhtar, A. Saqib, S. Asif, S. Bokhari, A. The present study aims to evaluate the feasibility of Maple Leaf Waste (MLW) for the first time to produce biofuel-bioenergy and chemicals. It is meaningful to understand the thermochemical conversion and degradation pattern of the MLW to evaluate its biofuel-bioenergy potential. Different degradation stages and zones based on temperature and mass loss were identified to understand the pyrolytic behaviour in depth. Four different heating rates were used to conduct kinetic and thermodynamic analysis. The pyrolysis temperature was concluded ranged from 200 °C to 430 °C at all heating rates to obtain maximum bioenergy products. The kinetic parameters of pyrolysis were obtained by analysing through iso-conversional models of Kissinger-Akahira-Sunose (KAS), Friedman and Flynn�Wall�Ozawa (FWO). The average values of activation energies (75�91 kJ mol�1), high heating values (16.32 MJ kg�1), Gibb's free energies (261�269 kJ mol�1) and change in enthalpy (68�85 kJ mol�1) have shown the significant potential for bioenergy production and suitability of co-pyrolysis with other waste and biomass feedstock. © 2021 Elsevier Ltd Elsevier Ltd 2021 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85101636207&doi=10.1016%2fj.fuel.2021.120349&partnerID=40&md5=68ce4582bd33d204f29206815b330492 Ahmad, M.S. and Klemeš, J.J. and Alhumade, H. and Elkamel, A. and Mahmood, A. and Shen, B. and Ibrahim, M. and Mukhtar, A. and Saqib, S. and Asif, S. and Bokhari, A. (2021) Thermo-kinetic study to elucidate the bioenergy potential of Maple Leaf Waste (MLW) by pyrolysis, TGA and kinetic modelling. Fuel, 293 . http://eprints.utp.edu.my/30360/
institution Universiti Teknologi Petronas
collection UTP Institutional Repository
description The present study aims to evaluate the feasibility of Maple Leaf Waste (MLW) for the first time to produce biofuel-bioenergy and chemicals. It is meaningful to understand the thermochemical conversion and degradation pattern of the MLW to evaluate its biofuel-bioenergy potential. Different degradation stages and zones based on temperature and mass loss were identified to understand the pyrolytic behaviour in depth. Four different heating rates were used to conduct kinetic and thermodynamic analysis. The pyrolysis temperature was concluded ranged from 200 °C to 430 °C at all heating rates to obtain maximum bioenergy products. The kinetic parameters of pyrolysis were obtained by analysing through iso-conversional models of Kissinger-Akahira-Sunose (KAS), Friedman and Flynn�Wall�Ozawa (FWO). The average values of activation energies (75�91 kJ mol�1), high heating values (16.32 MJ kg�1), Gibb's free energies (261�269 kJ mol�1) and change in enthalpy (68�85 kJ mol�1) have shown the significant potential for bioenergy production and suitability of co-pyrolysis with other waste and biomass feedstock. © 2021 Elsevier Ltd
format Article
author Ahmad, M.S.
Klemeš, J.J.
Alhumade, H.
Elkamel, A.
Mahmood, A.
Shen, B.
Ibrahim, M.
Mukhtar, A.
Saqib, S.
Asif, S.
Bokhari, A.
spellingShingle Ahmad, M.S.
Klemeš, J.J.
Alhumade, H.
Elkamel, A.
Mahmood, A.
Shen, B.
Ibrahim, M.
Mukhtar, A.
Saqib, S.
Asif, S.
Bokhari, A.
Thermo-kinetic study to elucidate the bioenergy potential of Maple Leaf Waste (MLW) by pyrolysis, TGA and kinetic modelling
author_sort Ahmad, M.S.
title Thermo-kinetic study to elucidate the bioenergy potential of Maple Leaf Waste (MLW) by pyrolysis, TGA and kinetic modelling
title_short Thermo-kinetic study to elucidate the bioenergy potential of Maple Leaf Waste (MLW) by pyrolysis, TGA and kinetic modelling
title_full Thermo-kinetic study to elucidate the bioenergy potential of Maple Leaf Waste (MLW) by pyrolysis, TGA and kinetic modelling
title_fullStr Thermo-kinetic study to elucidate the bioenergy potential of Maple Leaf Waste (MLW) by pyrolysis, TGA and kinetic modelling
title_full_unstemmed Thermo-kinetic study to elucidate the bioenergy potential of Maple Leaf Waste (MLW) by pyrolysis, TGA and kinetic modelling
title_sort thermo-kinetic study to elucidate the bioenergy potential of maple leaf waste (mlw) by pyrolysis, tga and kinetic modelling
publisher Elsevier Ltd
publishDate 2021
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85101636207&doi=10.1016%2fj.fuel.2021.120349&partnerID=40&md5=68ce4582bd33d204f29206815b330492
http://eprints.utp.edu.my/30360/
_version_ 1741197393277222912
score 11.62408

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