Reforming of glycerol for hydrogen production over Ni based catalysts: Effect of support type

This current work focuses on hydrogen production that is a component in syngas by glycerol dry reforming over 15 nickel (Ni) loading supported on different oxides, namely CaO, ZrO2, and La2O3. The screening process was conducted in a fixed-bed reactor at 700°C under atmospheric pressure. It was foun...

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Main Authors: Mohd Arif, N.N., Harun, N., Yunus, N.M., Vo, D.-V.N., Azizan, M.T., Zainal Abidin, S.
Format: Article
Institution: Universiti Teknologi Petronas
Record Id / ISBN-0: utp-eprints.19539 /
Published: Taylor and Francis Inc. 2017
Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85015107294&doi=10.1080%2f15567036.2016.1244580&partnerID=40&md5=85010eb47f7f93f8357d853fe701f736
http://eprints.utp.edu.my/19539/
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spelling utp-eprints.195392018-04-20T06:50:38Z Reforming of glycerol for hydrogen production over Ni based catalysts: Effect of support type Mohd Arif, N.N. Harun, N. Yunus, N.M. Vo, D.-V.N. Azizan, M.T. Zainal Abidin, S. This current work focuses on hydrogen production that is a component in syngas by glycerol dry reforming over 15 nickel (Ni) loading supported on different oxides, namely CaO, ZrO2, and La2O3. The screening process was conducted in a fixed-bed reactor at 700°C under atmospheric pressure. It was found that 15 Ni/CaO showed the best performance in screening studies. The effect of temperature and the carbon to glycerol ratio (CGR) was then analyzed for this catalyst. From the analysis, it was seen that 15 Ni/CaO has its optimum condition at 800°C and CGR = 1, where it gives the highest glycerol conversion (XG = 37.66) and hydrogen yield (YH = 32.45). © 2017 Taylor & Francis Group, LLC. Taylor and Francis Inc. 2017 Article PeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85015107294&doi=10.1080%2f15567036.2016.1244580&partnerID=40&md5=85010eb47f7f93f8357d853fe701f736 Mohd Arif, N.N. and Harun, N. and Yunus, N.M. and Vo, D.-V.N. and Azizan, M.T. and Zainal Abidin, S. (2017) Reforming of glycerol for hydrogen production over Ni based catalysts: Effect of support type. Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 39 (7). pp. 657-663. http://eprints.utp.edu.my/19539/
institution Universiti Teknologi Petronas
collection UTP Institutional Repository
description This current work focuses on hydrogen production that is a component in syngas by glycerol dry reforming over 15 nickel (Ni) loading supported on different oxides, namely CaO, ZrO2, and La2O3. The screening process was conducted in a fixed-bed reactor at 700°C under atmospheric pressure. It was found that 15 Ni/CaO showed the best performance in screening studies. The effect of temperature and the carbon to glycerol ratio (CGR) was then analyzed for this catalyst. From the analysis, it was seen that 15 Ni/CaO has its optimum condition at 800°C and CGR = 1, where it gives the highest glycerol conversion (XG = 37.66) and hydrogen yield (YH = 32.45). © 2017 Taylor & Francis Group, LLC.
format Article
author Mohd Arif, N.N.
Harun, N.
Yunus, N.M.
Vo, D.-V.N.
Azizan, M.T.
Zainal Abidin, S.
spellingShingle Mohd Arif, N.N.
Harun, N.
Yunus, N.M.
Vo, D.-V.N.
Azizan, M.T.
Zainal Abidin, S.
Reforming of glycerol for hydrogen production over Ni based catalysts: Effect of support type
author_sort Mohd Arif, N.N.
title Reforming of glycerol for hydrogen production over Ni based catalysts: Effect of support type
title_short Reforming of glycerol for hydrogen production over Ni based catalysts: Effect of support type
title_full Reforming of glycerol for hydrogen production over Ni based catalysts: Effect of support type
title_fullStr Reforming of glycerol for hydrogen production over Ni based catalysts: Effect of support type
title_full_unstemmed Reforming of glycerol for hydrogen production over Ni based catalysts: Effect of support type
title_sort reforming of glycerol for hydrogen production over ni based catalysts: effect of support type
publisher Taylor and Francis Inc.
publishDate 2017
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85015107294&doi=10.1080%2f15567036.2016.1244580&partnerID=40&md5=85010eb47f7f93f8357d853fe701f736
http://eprints.utp.edu.my/19539/
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score 11.62408