Effects of amine-functionalization on mixed matrix membranes encompassing of T-type zeolite and 6FDA-based polyimide for separation of CO2 from CH4

Mixed matrix membranes (MMMs) comprising of unfunctionalized and amine-functionalized T-type zeolite and 6FDA-based polyimide matrix were formulated. The physicochemical properties of the membranes were examined by FESEM, EDX, TGA and DSC. FESEM images showed that the enhancement of polymer-zeolite...

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Main Authors: Jusoh, N., Yeong, Y.F., Lau, K.K., Shariff, A.M.
Format: Article
Institution: Universiti Teknologi Petronas
Record Id / ISBN-0: utp-eprints.20555 /
Published: Universiti Malaysia Pahang 2018
Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85048317728&doi=10.15282%2fijame.15.1.2018.17.0396&partnerID=40&md5=2e17abc89dc3af0f423c7db9ee27aced
http://eprints.utp.edu.my/20555/
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spelling utp-eprints.205552018-10-11T01:47:14Z Effects of amine-functionalization on mixed matrix membranes encompassing of T-type zeolite and 6FDA-based polyimide for separation of CO2 from CH4 Jusoh, N. Yeong, Y.F. Lau, K.K. Shariff, A.M. Mixed matrix membranes (MMMs) comprising of unfunctionalized and amine-functionalized T-type zeolite and 6FDA-based polyimide matrix were formulated. The physicochemical properties of the membranes were examined by FESEM, EDX, TGA and DSC. FESEM images showed that the enhancement of polymer-zeolite adhesion in MMM embedded with amine-functionalized T-type zeolite is trivial in comparison with MMM loaded with unfunctionalized T-type zeolite. From permeation test, permeability of CO2 of 858 Barrer and selectivity of CO2/CH4 of 22.5 was obtained using MMM incorporated with amine-functionalized T-type zeolite, whereas MMM incorporated with unfunctionalized T-type zeolite displayed permeability of CO2 of 844 Barrer and selectivity of CO2/CH4 of 19.1. Thus, selection of another suitable amine-functionalization group might be required in later works to further improve MMM performance in capturing CO2 from CH4. © Universiti Malaysia Pahang, Malaysia. Universiti Malaysia Pahang 2018 Article PeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85048317728&doi=10.15282%2fijame.15.1.2018.17.0396&partnerID=40&md5=2e17abc89dc3af0f423c7db9ee27aced Jusoh, N. and Yeong, Y.F. and Lau, K.K. and Shariff, A.M. (2018) Effects of amine-functionalization on mixed matrix membranes encompassing of T-type zeolite and 6FDA-based polyimide for separation of CO2 from CH4. International Journal of Automotive and Mechanical Engineering, 15 (1). pp. 5126-5134. http://eprints.utp.edu.my/20555/
institution Universiti Teknologi Petronas
collection UTP Institutional Repository
description Mixed matrix membranes (MMMs) comprising of unfunctionalized and amine-functionalized T-type zeolite and 6FDA-based polyimide matrix were formulated. The physicochemical properties of the membranes were examined by FESEM, EDX, TGA and DSC. FESEM images showed that the enhancement of polymer-zeolite adhesion in MMM embedded with amine-functionalized T-type zeolite is trivial in comparison with MMM loaded with unfunctionalized T-type zeolite. From permeation test, permeability of CO2 of 858 Barrer and selectivity of CO2/CH4 of 22.5 was obtained using MMM incorporated with amine-functionalized T-type zeolite, whereas MMM incorporated with unfunctionalized T-type zeolite displayed permeability of CO2 of 844 Barrer and selectivity of CO2/CH4 of 19.1. Thus, selection of another suitable amine-functionalization group might be required in later works to further improve MMM performance in capturing CO2 from CH4. © Universiti Malaysia Pahang, Malaysia.
format Article
author Jusoh, N.
Yeong, Y.F.
Lau, K.K.
Shariff, A.M.
spellingShingle Jusoh, N.
Yeong, Y.F.
Lau, K.K.
Shariff, A.M.
Effects of amine-functionalization on mixed matrix membranes encompassing of T-type zeolite and 6FDA-based polyimide for separation of CO2 from CH4
author_sort Jusoh, N.
title Effects of amine-functionalization on mixed matrix membranes encompassing of T-type zeolite and 6FDA-based polyimide for separation of CO2 from CH4
title_short Effects of amine-functionalization on mixed matrix membranes encompassing of T-type zeolite and 6FDA-based polyimide for separation of CO2 from CH4
title_full Effects of amine-functionalization on mixed matrix membranes encompassing of T-type zeolite and 6FDA-based polyimide for separation of CO2 from CH4
title_fullStr Effects of amine-functionalization on mixed matrix membranes encompassing of T-type zeolite and 6FDA-based polyimide for separation of CO2 from CH4
title_full_unstemmed Effects of amine-functionalization on mixed matrix membranes encompassing of T-type zeolite and 6FDA-based polyimide for separation of CO2 from CH4
title_sort effects of amine-functionalization on mixed matrix membranes encompassing of t-type zeolite and 6fda-based polyimide for separation of co2 from ch4
publisher Universiti Malaysia Pahang
publishDate 2018
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85048317728&doi=10.15282%2fijame.15.1.2018.17.0396&partnerID=40&md5=2e17abc89dc3af0f423c7db9ee27aced
http://eprints.utp.edu.my/20555/
_version_ 1741196359691665408
score 11.62408

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