Alkyd paint removal: Ionic liquid vs volatile organic compound (VOC)

The drive towards safer technology in removing paint from substrate requires switching from hazardous volatile organic compounds to greener alternative solvents. Ionic liquids (ILs) have been considered as relatively green solvents and employed in many applications. This study focusses on investigat...

Full description

Main Authors: Sarwono, A., Man, Z., Idris, A., Nee, T.H., Muhammad, N., Khan, A.S., Ullah, Z.
Format: Article
Institution: Universiti Teknologi Petronas
Record Id / ISBN-0: utp-eprints.20779 /
Published: Elsevier B.V. 2018
Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85047160525&doi=10.1016%2fj.porgcoat.2018.05.005&partnerID=40&md5=c4abd739af86cd85af4d16eee158e1a9
http://eprints.utp.edu.my/20779/
Tags: Add Tag
No Tags, Be the first to tag this record!
id utp-eprints.20779
recordtype eprints
spelling utp-eprints.207792019-02-26T02:24:04Z Alkyd paint removal: Ionic liquid vs volatile organic compound (VOC) Sarwono, A. Man, Z. Idris, A. Nee, T.H. Muhammad, N. Khan, A.S. Ullah, Z. The drive towards safer technology in removing paint from substrate requires switching from hazardous volatile organic compounds to greener alternative solvents. Ionic liquids (ILs) have been considered as relatively green solvents and employed in many applications. This study focusses on investigation of ILs as alternative green solvents for paint removal. In this regard, five imdazolium based ILs were studied for alkyd paint removal on coated wooden substrate. The effect of various anions such as dicyanamide DCA, bis (trifluoromethanesulfonyl) imide NTf2, hydrogen sulphate HSO4, acetate OAc and chloride Cl was investigated. For benchmarking and comparison, three volatile organic solvents such as toluene, acetonitrile, and ethanol were used. Microscopic images showed that DCA anion gave significant impact on alkyd removal. In addition, BmimDCA gave highest swelling percentage of 23% whereas the other ILs did not show significant swelling. Viscosity, anion size and alkyd paint-IL interactions played important roles in removal efficacy. The prolonged immersion time in BmimDCA decreased the pull off adhesion strength up to 83.3% and consecutively promoted paint detachment from substrate. Similar infrared pattern of bare wooden stick and BmimDCA treated coated wooden stick indicates significant removal of paint by IL. The experimental results demonstrate promising application of IL as a green solvent for paint removal. © 2018 Elsevier B.V. Elsevier B.V. 2018 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85047160525&doi=10.1016%2fj.porgcoat.2018.05.005&partnerID=40&md5=c4abd739af86cd85af4d16eee158e1a9 Sarwono, A. and Man, Z. and Idris, A. and Nee, T.H. and Muhammad, N. and Khan, A.S. and Ullah, Z. (2018) Alkyd paint removal: Ionic liquid vs volatile organic compound (VOC). Progress in Organic Coatings, 122 . pp. 79-87. http://eprints.utp.edu.my/20779/
institution Universiti Teknologi Petronas
collection UTP Institutional Repository
description The drive towards safer technology in removing paint from substrate requires switching from hazardous volatile organic compounds to greener alternative solvents. Ionic liquids (ILs) have been considered as relatively green solvents and employed in many applications. This study focusses on investigation of ILs as alternative green solvents for paint removal. In this regard, five imdazolium based ILs were studied for alkyd paint removal on coated wooden substrate. The effect of various anions such as dicyanamide DCA, bis (trifluoromethanesulfonyl) imide NTf2, hydrogen sulphate HSO4, acetate OAc and chloride Cl was investigated. For benchmarking and comparison, three volatile organic solvents such as toluene, acetonitrile, and ethanol were used. Microscopic images showed that DCA anion gave significant impact on alkyd removal. In addition, BmimDCA gave highest swelling percentage of 23% whereas the other ILs did not show significant swelling. Viscosity, anion size and alkyd paint-IL interactions played important roles in removal efficacy. The prolonged immersion time in BmimDCA decreased the pull off adhesion strength up to 83.3% and consecutively promoted paint detachment from substrate. Similar infrared pattern of bare wooden stick and BmimDCA treated coated wooden stick indicates significant removal of paint by IL. The experimental results demonstrate promising application of IL as a green solvent for paint removal. © 2018 Elsevier B.V.
format Article
author Sarwono, A.
Man, Z.
Idris, A.
Nee, T.H.
Muhammad, N.
Khan, A.S.
Ullah, Z.
spellingShingle Sarwono, A.
Man, Z.
Idris, A.
Nee, T.H.
Muhammad, N.
Khan, A.S.
Ullah, Z.
Alkyd paint removal: Ionic liquid vs volatile organic compound (VOC)
author_sort Sarwono, A.
title Alkyd paint removal: Ionic liquid vs volatile organic compound (VOC)
title_short Alkyd paint removal: Ionic liquid vs volatile organic compound (VOC)
title_full Alkyd paint removal: Ionic liquid vs volatile organic compound (VOC)
title_fullStr Alkyd paint removal: Ionic liquid vs volatile organic compound (VOC)
title_full_unstemmed Alkyd paint removal: Ionic liquid vs volatile organic compound (VOC)
title_sort alkyd paint removal: ionic liquid vs volatile organic compound (voc)
publisher Elsevier B.V.
publishDate 2018
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85047160525&doi=10.1016%2fj.porgcoat.2018.05.005&partnerID=40&md5=c4abd739af86cd85af4d16eee158e1a9
http://eprints.utp.edu.my/20779/
_version_ 1741196395218468864
score 11.62408

Similar Items