Optimization of ionic liquid assisted sugar conversion and nanofiltration membrane separation for 5-hydroxymethylfurfural

This paper provides complete loop of ionic liquid (IL) assisted glucose conversion to 5-hydroxymethylfurfural (HMF), nanofiltration membrane (NF) based separation and recyclability. The optimum HMF yield of 65.6 was obtained with 8 wt. catalyst loading at 125 °C reaction temperature in 120 min reac...

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Main Authors: Sarwono, A., Man, Z., Idris, A., Khan, A.S., Muhammad, N., Wilfred, C.D.
Format: Article
Institution: Universiti Teknologi Petronas
Record Id / ISBN-0: utp-eprints.22172 /
Published: 2019
Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85054031192&doi=10.1016%2fj.jiec.2018.09.020&partnerID=40&md5=f649aed11de414482793c5cb17fdb1f5
http://eprints.utp.edu.my/22172/
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spelling utp-eprints.221722019-02-28T05:17:11Z Optimization of ionic liquid assisted sugar conversion and nanofiltration membrane separation for 5-hydroxymethylfurfural Sarwono, A. Man, Z. Idris, A. Khan, A.S. Muhammad, N. Wilfred, C.D. This paper provides complete loop of ionic liquid (IL) assisted glucose conversion to 5-hydroxymethylfurfural (HMF), nanofiltration membrane (NF) based separation and recyclability. The optimum HMF yield of 65.6 was obtained with 8 wt. catalyst loading at 125 °C reaction temperature in 120 min reaction time. Ea for conversion was found to be 120 kJ/mol. NF was adopted first time to separate IL and HMF. The percentage of recovered HMF using NF for 1st, 2nd and 3rd batches are 94.87, 84.35 and 71.65 respectively. The structures of regenerated IL and HMF, obtained from NF and liquid�liquid extraction, were confirmed by NMR. © 2018 The Korean Society of Industrial and Engineering Chemistry 2019 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85054031192&doi=10.1016%2fj.jiec.2018.09.020&partnerID=40&md5=f649aed11de414482793c5cb17fdb1f5 Sarwono, A. and Man, Z. and Idris, A. and Khan, A.S. and Muhammad, N. and Wilfred, C.D. (2019) Optimization of ionic liquid assisted sugar conversion and nanofiltration membrane separation for 5-hydroxymethylfurfural. Journal of Industrial and Engineering Chemistry, 69 . pp. 171-178. http://eprints.utp.edu.my/22172/
institution Universiti Teknologi Petronas
collection UTP Institutional Repository
description This paper provides complete loop of ionic liquid (IL) assisted glucose conversion to 5-hydroxymethylfurfural (HMF), nanofiltration membrane (NF) based separation and recyclability. The optimum HMF yield of 65.6 was obtained with 8 wt. catalyst loading at 125 °C reaction temperature in 120 min reaction time. Ea for conversion was found to be 120 kJ/mol. NF was adopted first time to separate IL and HMF. The percentage of recovered HMF using NF for 1st, 2nd and 3rd batches are 94.87, 84.35 and 71.65 respectively. The structures of regenerated IL and HMF, obtained from NF and liquid�liquid extraction, were confirmed by NMR. © 2018 The Korean Society of Industrial and Engineering Chemistry
format Article
author Sarwono, A.
Man, Z.
Idris, A.
Khan, A.S.
Muhammad, N.
Wilfred, C.D.
spellingShingle Sarwono, A.
Man, Z.
Idris, A.
Khan, A.S.
Muhammad, N.
Wilfred, C.D.
Optimization of ionic liquid assisted sugar conversion and nanofiltration membrane separation for 5-hydroxymethylfurfural
author_sort Sarwono, A.
title Optimization of ionic liquid assisted sugar conversion and nanofiltration membrane separation for 5-hydroxymethylfurfural
title_short Optimization of ionic liquid assisted sugar conversion and nanofiltration membrane separation for 5-hydroxymethylfurfural
title_full Optimization of ionic liquid assisted sugar conversion and nanofiltration membrane separation for 5-hydroxymethylfurfural
title_fullStr Optimization of ionic liquid assisted sugar conversion and nanofiltration membrane separation for 5-hydroxymethylfurfural
title_full_unstemmed Optimization of ionic liquid assisted sugar conversion and nanofiltration membrane separation for 5-hydroxymethylfurfural
title_sort optimization of ionic liquid assisted sugar conversion and nanofiltration membrane separation for 5-hydroxymethylfurfural
publishDate 2019
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85054031192&doi=10.1016%2fj.jiec.2018.09.020&partnerID=40&md5=f649aed11de414482793c5cb17fdb1f5
http://eprints.utp.edu.my/22172/
_version_ 1741196579603218432
score 11.62408

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