Integrated photooxidative extractive deep desulfurization using metal doped TiO2 and eutectic based ionic liquid
A series of metal doped TiO2 namely Fe/TiO2, Cu/TiO2 and Cu-Fe/TiO2 were synthesized and characterized, to be used as a photocatalyst in the integrated photooxidative extractive deep desulfurization for model oil (dodecane) and diesel fuel. The order of the photocatalytic activity was Cu-Fe/TiO2 fol...
| Main Authors: | Zaid, H.F.M., Kait, C.F., Mutalib, M.I.A. |
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| Format: | Conference or Workshop Item |
| Institution: | Universiti Teknologi Petronas |
| Record Id / ISBN-0: | utp-eprints.30619 / |
| Published: |
American Institute of Physics Inc.
2016
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| Online Access: |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85006004682&doi=10.1063%2f1.4968072&partnerID=40&md5=cb2c1dd054186bfc147f0deb67b3fcf2 http://eprints.utp.edu.my/30619/ |
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| Summary: |
A series of metal doped TiO2 namely Fe/TiO2, Cu/TiO2 and Cu-Fe/TiO2 were synthesized and characterized, to be used as a photocatalyst in the integrated photooxidative extractive deep desulfurization for model oil (dodecane) and diesel fuel. The order of the photocatalytic activity was Cu-Fe/TiO2 followed by Cu/TiO2 and then Fe/TiO2. Cu-Fe/TiO2 was an effective photocatalyst for sulfur conversion at ambient atmospheric pressure. Hydrogen peroxide was used as the source of oxidant and eutectic-based ionic liquid as the extractant. Sulfur conversion in model oil reached 100. Removal of sulfur from model oil was done by two times extraction with a removal of 97.06 in the first run and 2.94 in the second run. © 2016 Author(s). |
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