Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes

Direct methanol fuel cells have attracted great interest in the recent development of portable devices. New routes are being developed for synthesizing the catalysts used in the methanol oxidation. In this work, the electrochemical behavior of the Pt and Pt-Ni upon multiwalled carbon nanotubes, synt...

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Main Authors: Mohammed, N.M., Mumtaz, A., Ansari, M.S., Ahmad, R.
Format: Conference or Workshop Item
Institution: Universiti Teknologi Petronas
Record Id / ISBN-0: utp-eprints.30650 /
Published: American Institute of Physics Inc. 2016
Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005966709&doi=10.1063%2f1.4968121&partnerID=40&md5=846d63bbbbaf2068066f8ff897946928
http://eprints.utp.edu.my/30650/
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spelling utp-eprints.306502022-03-25T07:13:35Z Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes Mohammed, N.M. Mumtaz, A. Ansari, M.S. Ahmad, R. Direct methanol fuel cells have attracted great interest in the recent development of portable devices. New routes are being developed for synthesizing the catalysts used in the methanol oxidation. In this work, the electrochemical behavior of the Pt and Pt-Ni upon multiwalled carbon nanotubes, synthesized via a new modified route, has been studied. The results showed that Pt-Ni 10 has the comparable current density to the Pt 20-loading which is nearly 3 times greater than 10 Pt loading. The transfer of the polarization curve of Pt-Ni 10 towards lower polarization region following the catalyst with 20 Pt loading indicates the higher activity of the nano-electro-catalysts in the alkaline media. Also the long term efficiency and activity of the Pt-Ni with 10 loading is nearly reaching the 20 Pt-loading which is almost 10 folds greater than the 10 Pt loading. The study revealed that Ni in Pt-based nanoalloy impart not only an enhanced activity but also better durability of catalyst in direct methanol fuel cell applications. © 2016 Author(s). American Institute of Physics Inc. 2016 Conference or Workshop Item NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005966709&doi=10.1063%2f1.4968121&partnerID=40&md5=846d63bbbbaf2068066f8ff897946928 Mohammed, N.M. and Mumtaz, A. and Ansari, M.S. and Ahmad, R. (2016) Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes. In: UNSPECIFIED. http://eprints.utp.edu.my/30650/
institution Universiti Teknologi Petronas
collection UTP Institutional Repository
description Direct methanol fuel cells have attracted great interest in the recent development of portable devices. New routes are being developed for synthesizing the catalysts used in the methanol oxidation. In this work, the electrochemical behavior of the Pt and Pt-Ni upon multiwalled carbon nanotubes, synthesized via a new modified route, has been studied. The results showed that Pt-Ni 10 has the comparable current density to the Pt 20-loading which is nearly 3 times greater than 10 Pt loading. The transfer of the polarization curve of Pt-Ni 10 towards lower polarization region following the catalyst with 20 Pt loading indicates the higher activity of the nano-electro-catalysts in the alkaline media. Also the long term efficiency and activity of the Pt-Ni with 10 loading is nearly reaching the 20 Pt-loading which is almost 10 folds greater than the 10 Pt loading. The study revealed that Ni in Pt-based nanoalloy impart not only an enhanced activity but also better durability of catalyst in direct methanol fuel cell applications. © 2016 Author(s).
format Conference or Workshop Item
author Mohammed, N.M.
Mumtaz, A.
Ansari, M.S.
Ahmad, R.
spellingShingle Mohammed, N.M.
Mumtaz, A.
Ansari, M.S.
Ahmad, R.
Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes
author_sort Mohammed, N.M.
title Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes
title_short Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes
title_full Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes
title_fullStr Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes
title_full_unstemmed Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes
title_sort electrochemical study of the pt and pt-ni upon multiwalled carbon nanotubes
publisher American Institute of Physics Inc.
publishDate 2016
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005966709&doi=10.1063%2f1.4968121&partnerID=40&md5=846d63bbbbaf2068066f8ff897946928
http://eprints.utp.edu.my/30650/
_version_ 1741197443290103808
score 11.62408