Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes
Direct methanol fuel cells have attracted great interest in the recent development of portable devices. New routes are being developed for synthesizing the catalysts used in the methanol oxidation. In this work, the electrochemical behavior of the Pt and Pt-Ni upon multiwalled carbon nanotubes, synt...
| Main Authors: | Mohammed, N.M., Mumtaz, A., Ansari, M.S., Ahmad, R. |
|---|---|
| Format: | Conference or Workshop Item |
| Institution: | Universiti Teknologi Petronas |
| Record Id / ISBN-0: | utp-eprints.30650 / |
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American Institute of Physics Inc.
2016
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005966709&doi=10.1063%2f1.4968121&partnerID=40&md5=846d63bbbbaf2068066f8ff897946928 http://eprints.utp.edu.my/30650/ |
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utp-eprints.306502022-03-25T07:13:35Z Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes Mohammed, N.M. Mumtaz, A. Ansari, M.S. Ahmad, R. Direct methanol fuel cells have attracted great interest in the recent development of portable devices. New routes are being developed for synthesizing the catalysts used in the methanol oxidation. In this work, the electrochemical behavior of the Pt and Pt-Ni upon multiwalled carbon nanotubes, synthesized via a new modified route, has been studied. The results showed that Pt-Ni 10 has the comparable current density to the Pt 20-loading which is nearly 3 times greater than 10 Pt loading. The transfer of the polarization curve of Pt-Ni 10 towards lower polarization region following the catalyst with 20 Pt loading indicates the higher activity of the nano-electro-catalysts in the alkaline media. Also the long term efficiency and activity of the Pt-Ni with 10 loading is nearly reaching the 20 Pt-loading which is almost 10 folds greater than the 10 Pt loading. The study revealed that Ni in Pt-based nanoalloy impart not only an enhanced activity but also better durability of catalyst in direct methanol fuel cell applications. © 2016 Author(s). American Institute of Physics Inc. 2016 Conference or Workshop Item NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005966709&doi=10.1063%2f1.4968121&partnerID=40&md5=846d63bbbbaf2068066f8ff897946928 Mohammed, N.M. and Mumtaz, A. and Ansari, M.S. and Ahmad, R. (2016) Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes. In: UNSPECIFIED. http://eprints.utp.edu.my/30650/ |
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Universiti Teknologi Petronas |
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UTP Institutional Repository |
| description |
Direct methanol fuel cells have attracted great interest in the recent development of portable devices. New routes are being developed for synthesizing the catalysts used in the methanol oxidation. In this work, the electrochemical behavior of the Pt and Pt-Ni upon multiwalled carbon nanotubes, synthesized via a new modified route, has been studied. The results showed that Pt-Ni 10 has the comparable current density to the Pt 20-loading which is nearly 3 times greater than 10 Pt loading. The transfer of the polarization curve of Pt-Ni 10 towards lower polarization region following the catalyst with 20 Pt loading indicates the higher activity of the nano-electro-catalysts in the alkaline media. Also the long term efficiency and activity of the Pt-Ni with 10 loading is nearly reaching the 20 Pt-loading which is almost 10 folds greater than the 10 Pt loading. The study revealed that Ni in Pt-based nanoalloy impart not only an enhanced activity but also better durability of catalyst in direct methanol fuel cell applications. © 2016 Author(s). |
| format |
Conference or Workshop Item |
| author |
Mohammed, N.M. Mumtaz, A. Ansari, M.S. Ahmad, R. |
| spellingShingle |
Mohammed, N.M. Mumtaz, A. Ansari, M.S. Ahmad, R. Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes |
| author_sort |
Mohammed, N.M. |
| title |
Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes |
| title_short |
Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes |
| title_full |
Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes |
| title_fullStr |
Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes |
| title_full_unstemmed |
Electrochemical study of the Pt and Pt-Ni upon multiwalled carbon nanotubes |
| title_sort |
electrochemical study of the pt and pt-ni upon multiwalled carbon nanotubes |
| publisher |
American Institute of Physics Inc. |
| publishDate |
2016 |
| url |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85005966709&doi=10.1063%2f1.4968121&partnerID=40&md5=846d63bbbbaf2068066f8ff897946928 http://eprints.utp.edu.my/30650/ |
| _version_ |
1741197443290103808 |
| score |
11.62408 |