Effect of ball milling on the catalytic conversion of cellulose to levulinic acid
The yield of levulinic acid from cellulose is very low because of a strong network of intera- and intermolecular hydrogen bonding. Ball milling cause significant decrease in the cellulose crystalinity and thus increase the production of levulinic acid (LA) by using Aluminum Chloride (AlCl3) as a cat...
| Main Authors: | Khan, A.S., Man, Z.B., Bustam Khalil, M.A., Kait, C.F., Maulud, A.S. |
|---|---|
| Format: | Article |
| Institution: | Universiti Teknologi Petronas |
| Record Id / ISBN-0: | utp-eprints.31904 / |
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Trans Tech Publications Ltd
2014
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https://www.scopus.com/inward/record.uri?eid=2-s2.0-84914160306&doi=10.4028%2fwww.scientific.net%2fAMM.625.353&partnerID=40&md5=fc55d5f38c9e499c278a3b5372441bb8 http://eprints.utp.edu.my/31904/ |
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utp-eprints.319042022-03-29T03:39:48Z Effect of ball milling on the catalytic conversion of cellulose to levulinic acid Khan, A.S. Man, Z.B. Bustam Khalil, M.A. Kait, C.F. Maulud, A.S. The yield of levulinic acid from cellulose is very low because of a strong network of intera- and intermolecular hydrogen bonding. Ball milling cause significant decrease in the cellulose crystalinity and thus increase the production of levulinic acid (LA) by using Aluminum Chloride (AlCl3) as a catalyst. By means of AlCl3 depolymerization, cellulose can produce 5- Hydroxymethylfurfural (5-HMF) and subsequently LA. The effect of reaction temperature and time were investigated. The maximum yield of LA (36.5 mol ) was achieved using 180 ͦC and 240 min. © 2014 Trans Tech Publications, Switzerland. Trans Tech Publications Ltd 2014 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-84914160306&doi=10.4028%2fwww.scientific.net%2fAMM.625.353&partnerID=40&md5=fc55d5f38c9e499c278a3b5372441bb8 Khan, A.S. and Man, Z.B. and Bustam Khalil, M.A. and Kait, C.F. and Maulud, A.S. (2014) Effect of ball milling on the catalytic conversion of cellulose to levulinic acid. Applied Mechanics and Materials, 625 . pp. 353-356. http://eprints.utp.edu.my/31904/ |
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| description |
The yield of levulinic acid from cellulose is very low because of a strong network of intera- and intermolecular hydrogen bonding. Ball milling cause significant decrease in the cellulose crystalinity and thus increase the production of levulinic acid (LA) by using Aluminum Chloride (AlCl3) as a catalyst. By means of AlCl3 depolymerization, cellulose can produce 5- Hydroxymethylfurfural (5-HMF) and subsequently LA. The effect of reaction temperature and time were investigated. The maximum yield of LA (36.5 mol ) was achieved using 180 ͦC and 240 min. © 2014 Trans Tech Publications, Switzerland. |
| format |
Article |
| author |
Khan, A.S. Man, Z.B. Bustam Khalil, M.A. Kait, C.F. Maulud, A.S. |
| spellingShingle |
Khan, A.S. Man, Z.B. Bustam Khalil, M.A. Kait, C.F. Maulud, A.S. Effect of ball milling on the catalytic conversion of cellulose to levulinic acid |
| author_sort |
Khan, A.S. |
| title |
Effect of ball milling on the catalytic conversion of cellulose to levulinic acid |
| title_short |
Effect of ball milling on the catalytic conversion of cellulose to levulinic acid |
| title_full |
Effect of ball milling on the catalytic conversion of cellulose to levulinic acid |
| title_fullStr |
Effect of ball milling on the catalytic conversion of cellulose to levulinic acid |
| title_full_unstemmed |
Effect of ball milling on the catalytic conversion of cellulose to levulinic acid |
| title_sort |
effect of ball milling on the catalytic conversion of cellulose to levulinic acid |
| publisher |
Trans Tech Publications Ltd |
| publishDate |
2014 |
| url |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-84914160306&doi=10.4028%2fwww.scientific.net%2fAMM.625.353&partnerID=40&md5=fc55d5f38c9e499c278a3b5372441bb8 http://eprints.utp.edu.my/31904/ |
| _version_ |
1741197657848676352 |
| score |
11.62408 |