Utilization of indigenous gurgure (Monotheca Buxifolia) waste seeds as a potential feedstock for biodiesel production using environmentally benign bismuth modified CaO catalyst

Herein, we report the synthesis of Bi2O3 modified CaO heterogeneous catalyst for biodiesel production from low valued gurgure (Monotheca Buxifolia) seed oil to develop profitable and sustainable approach. The catalysts were analyzed by X-ray diffractometer (XRD), Brunauer-Emmett-Teller (BET), Temper...

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Main Authors: Farooq, M., Ramli, A., gul , M., Naeem, A., Perveen, F., Khan, I.W., Saeed, S., Sahar, J., Abid, G.
Format: Article
Institution: Universiti Teknologi Petronas
Record Id / ISBN-0: utp-eprints.33074 /
Published: Institution of Chemical Engineers 2022
Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-85130516465&doi=10.1016%2fj.cherd.2022.04.022&partnerID=40&md5=ccdb8ceebcea9dffeca1a8e71bd89920
http://eprints.utp.edu.my/33074/
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spelling utp-eprints.330742022-06-09T08:20:23Z Utilization of indigenous gurgure (Monotheca Buxifolia) waste seeds as a potential feedstock for biodiesel production using environmentally benign bismuth modified CaO catalyst Farooq, M. Ramli, A. gul , M. Naeem, A. Perveen, F. Khan, I.W. Saeed, S. Sahar, J. Abid, G. Herein, we report the synthesis of Bi2O3 modified CaO heterogeneous catalyst for biodiesel production from low valued gurgure (Monotheca Buxifolia) seed oil to develop profitable and sustainable approach. The catalysts were analyzed by X-ray diffractometer (XRD), Brunauer-Emmett-Teller (BET), Temperature programming desorption of CO2 (TPD-CO2), Field emission scanning electron microscopy (FESEM), Energy dispersive X-ray (EDX). The activity evaluation results indicated that the CaO-Bi2O3 catalyst enriched with 20 wt Bi2O3 loading displayed an excellent catalytic performance providing biodiesel yield of 98.7 under optimum reaction parameters of oil to methanol molar ratio 1:12, 65 °C reaction temperature in 2 hr of reaction time and catalyst loading of 6 wt. The catalyst depicted better reusability upto six reaction cycles and hence the cost of the biodiesel could be reduced effectively. Response surface methodology (RSM) based on central composite design (CCD) was also applied to investigate the influence of reaction parameters. The statistical deign results showed good consistent with the experimental data, providing p-vale of 0.000 i.e. high level of significance of the model. Finally, it could be summarized that the synthesized catalyst demonstrated remarkable activity and durability in term of biodiesel yield using gurguray oil as a cheap and non-edible feedstock. © 2022 Institution of Chemical Engineers Institution of Chemical Engineers 2022 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-85130516465&doi=10.1016%2fj.cherd.2022.04.022&partnerID=40&md5=ccdb8ceebcea9dffeca1a8e71bd89920 Farooq, M. and Ramli, A. and gul , M. and Naeem, A. and Perveen, F. and Khan, I.W. and Saeed, S. and Sahar, J. and Abid, G. (2022) Utilization of indigenous gurgure (Monotheca Buxifolia) waste seeds as a potential feedstock for biodiesel production using environmentally benign bismuth modified CaO catalyst. Chemical Engineering Research and Design, 183 . pp. 67-76. http://eprints.utp.edu.my/33074/
institution Universiti Teknologi Petronas
collection UTP Institutional Repository
description Herein, we report the synthesis of Bi2O3 modified CaO heterogeneous catalyst for biodiesel production from low valued gurgure (Monotheca Buxifolia) seed oil to develop profitable and sustainable approach. The catalysts were analyzed by X-ray diffractometer (XRD), Brunauer-Emmett-Teller (BET), Temperature programming desorption of CO2 (TPD-CO2), Field emission scanning electron microscopy (FESEM), Energy dispersive X-ray (EDX). The activity evaluation results indicated that the CaO-Bi2O3 catalyst enriched with 20 wt Bi2O3 loading displayed an excellent catalytic performance providing biodiesel yield of 98.7 under optimum reaction parameters of oil to methanol molar ratio 1:12, 65 °C reaction temperature in 2 hr of reaction time and catalyst loading of 6 wt. The catalyst depicted better reusability upto six reaction cycles and hence the cost of the biodiesel could be reduced effectively. Response surface methodology (RSM) based on central composite design (CCD) was also applied to investigate the influence of reaction parameters. The statistical deign results showed good consistent with the experimental data, providing p-vale of 0.000 i.e. high level of significance of the model. Finally, it could be summarized that the synthesized catalyst demonstrated remarkable activity and durability in term of biodiesel yield using gurguray oil as a cheap and non-edible feedstock. © 2022 Institution of Chemical Engineers
format Article
author Farooq, M.
Ramli, A.
gul , M.
Naeem, A.
Perveen, F.
Khan, I.W.
Saeed, S.
Sahar, J.
Abid, G.
spellingShingle Farooq, M.
Ramli, A.
gul , M.
Naeem, A.
Perveen, F.
Khan, I.W.
Saeed, S.
Sahar, J.
Abid, G.
Utilization of indigenous gurgure (Monotheca Buxifolia) waste seeds as a potential feedstock for biodiesel production using environmentally benign bismuth modified CaO catalyst
author_sort Farooq, M.
title Utilization of indigenous gurgure (Monotheca Buxifolia) waste seeds as a potential feedstock for biodiesel production using environmentally benign bismuth modified CaO catalyst
title_short Utilization of indigenous gurgure (Monotheca Buxifolia) waste seeds as a potential feedstock for biodiesel production using environmentally benign bismuth modified CaO catalyst
title_full Utilization of indigenous gurgure (Monotheca Buxifolia) waste seeds as a potential feedstock for biodiesel production using environmentally benign bismuth modified CaO catalyst
title_fullStr Utilization of indigenous gurgure (Monotheca Buxifolia) waste seeds as a potential feedstock for biodiesel production using environmentally benign bismuth modified CaO catalyst
title_full_unstemmed Utilization of indigenous gurgure (Monotheca Buxifolia) waste seeds as a potential feedstock for biodiesel production using environmentally benign bismuth modified CaO catalyst
title_sort utilization of indigenous gurgure (monotheca buxifolia) waste seeds as a potential feedstock for biodiesel production using environmentally benign bismuth modified cao catalyst
publisher Institution of Chemical Engineers
publishDate 2022
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-85130516465&doi=10.1016%2fj.cherd.2022.04.022&partnerID=40&md5=ccdb8ceebcea9dffeca1a8e71bd89920
http://eprints.utp.edu.my/33074/
_version_ 1741197799318355968
score 11.62408

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