HYDRODEOXYGENATION OF METHYL OLEATE INTO DIESEL-LIKE HYDROCARBONS OVERPd/SBA-15 CATALYSTS
Hydrodeoxygenation of vegetable oil has a potential to be converted into renewable and carbon-neutral fuel-like hydrocarbons. This present study focuses on generation of diesel range of hydrocarbons (C15 - Cig) from hydrodeoxygenation of 70% technical grade of methyl oleate over the in-house fabr...
| Main Author: | LEE, SIEW PEI |
|---|---|
| Format: | Thesis |
| Language: | English |
| Institution: | Universiti Teknologi Petronas |
| Record Id / ISBN-0: | utp-utpedia.21954 / |
| Published: |
2013
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| Subjects: | |
| Online Access: |
http://utpedia.utp.edu.my/21954/1/2013-CHEMICAL-HYDRODEOXYGENATION%20OF%20METHYL%20OLEATE%20INTO%20DIESEL-LIKE%20HYDROCARBONS%20OVER%20Pd%2CSBA-15%20CATALYSTS-LEE%20SIEW%20PEI.pdf http://utpedia.utp.edu.my/21954/ |
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| Summary: |
Hydrodeoxygenation of vegetable oil has a potential to be converted into renewable
and carbon-neutral fuel-like hydrocarbons. This present study focuses on generation
of diesel range of hydrocarbons (C15 - Cig) from hydrodeoxygenation of 70%
technical grade of methyl oleate over the in-house fabricated Pd/SBA-15 using
autoclave reactor. Two different morphologies of well-ordered hexagonal structure
SBA-15 were synthesized, that were necklace-like and rod-like structures. The
morphologies and physiochemical properties of the products were found to be greatly
affected by the shearing stress exerted in the synthesis mixture. Necklace-like SBA-
15 comprised of a bundle of individual rodlike silicas units provided larger surface
area than rod-like SBA-15. |
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