Development of Eutectic Ionic Liquids as an Electrolyte in Dye-Sensitized Solar Cells (DSSCs)

Ionic liquids (ILs) have been widely used as an electrolyte in dye sensitized solar cells (DSSCs) to replace the organic solvents due to their non-flammability, chemical and thermal stability as well as less prone to evaporation and leakage. However, some of the ILs possessed high viscosity and low...

Full description

Main Author: MOHD FARIDZ HILMY, NURFATHIAH IZZATY
Format: Thesis
Language: English
Institution: Universiti Teknologi Petronas
Record Id / ISBN-0: utp-utpedia.22782 /
Published: 2021
Subjects:
TP Chemical technology
Online Access: http://utpedia.utp.edu.my/22782/1/NURFATHIAH%20IZZATY%20MOHD%20FARIDZ%20HILMY_18002858.pdf
http://utpedia.utp.edu.my/22782/
Tags: Add Tag
No Tags, Be the first to tag this record!
id utp-utpedia.22782
recordtype eprints
spelling utp-utpedia.227822022-02-27T04:31:50Z http://utpedia.utp.edu.my/22782/ Development of Eutectic Ionic Liquids as an Electrolyte in Dye-Sensitized Solar Cells (DSSCs) MOHD FARIDZ HILMY, NURFATHIAH IZZATY TP Chemical technology Ionic liquids (ILs) have been widely used as an electrolyte in dye sensitized solar cells (DSSCs) to replace the organic solvents due to their non-flammability, chemical and thermal stability as well as less prone to evaporation and leakage. However, some of the ILs possessed high viscosity and low ionic conductivity. Therefore, the target of this study is to develop eutectic ILs mixture as an electrolyte with low viscosity, high ionic conductivity and able to be operated at room temperature conditions. In this work, a series of eutectic ILs mixtures composed of 1-ethyl-3-methylimidazolium iodide [C2C1mim] I, 1-ethylpyridinium iodide [C2py]I, 1-propylpyridinium [C3py]I and 1-butylpyridinium iodide [C4py]I were developed and characterized as potential electrolytes in DSSCs. The eutectic ILs mixtures are mixed at different ratios to evaluate their thermodynamic behavior and physicochemical properties. The melting temperature of pure ILs and the mixtures were determined using differential scanning calorimetry (DSC) in the temperature range of 123.15 K to 393.15 K. It is found that eutectic mixtures were formed at the molar ratios of {0.75[C2py]I : 0.25[C2C1im]I}, {0.25[C2py]I : 0.75[C2C1im]I}, {0.50[C2py]I : 0.50[C2C1im]I}, {0.75[C4py]I : 0.25[C2C1im]I}, {0.25[C4py]I : 0.75[C2C1im]I} and {0.50[C4py]I : 0.50[C2C1im]I} with the latter forming a highly stable liquid with no apparent melting peak in the studied temperature range. To understand the formation of eutectic composition, a correlation between molecular structures and the interaction energies of the cations and anions of ILs was performed using Conductor-like Screening Model for Real Solvents (COSMO-RS). Dynamic viscosities of the binary mixtures and eutectic ILs electrolytes were evaluated in the temperature range of 283.15 K to 353.15 K with 10 K increments. The highest ionic conductivity was exhibited by the eutectic ILs electrolyte {0.50[C2C1im] I:0.50[C4py] I: I2 (50 wt%)} at 9.67 mS·cm−1. Further photovoltaic performance evaluation of fabricated DSSCs showed a power conversion of 0.51% short circuit current, JSC at 2.68 mA/cm2 and open-circuit voltage, VOC of 0.43 V demonstrating its potential for electrolyte application in DSSC. 2021-07 Thesis NonPeerReviewed application/pdf en http://utpedia.utp.edu.my/22782/1/NURFATHIAH%20IZZATY%20MOHD%20FARIDZ%20HILMY_18002858.pdf MOHD FARIDZ HILMY, NURFATHIAH IZZATY (2021) Development of Eutectic Ionic Liquids as an Electrolyte in Dye-Sensitized Solar Cells (DSSCs). Masters thesis, Universiti Teknologi PETRONAS.
institution Universiti Teknologi Petronas
collection UTPedia
language English
topic TP Chemical technology
spellingShingle TP Chemical technology
MOHD FARIDZ HILMY, NURFATHIAH IZZATY
Development of Eutectic Ionic Liquids as an Electrolyte in Dye-Sensitized Solar Cells (DSSCs)
description Ionic liquids (ILs) have been widely used as an electrolyte in dye sensitized solar cells (DSSCs) to replace the organic solvents due to their non-flammability, chemical and thermal stability as well as less prone to evaporation and leakage. However, some of the ILs possessed high viscosity and low ionic conductivity. Therefore, the target of this study is to develop eutectic ILs mixture as an electrolyte with low viscosity, high ionic conductivity and able to be operated at room temperature conditions. In this work, a series of eutectic ILs mixtures composed of 1-ethyl-3-methylimidazolium iodide [C2C1mim] I, 1-ethylpyridinium iodide [C2py]I, 1-propylpyridinium [C3py]I and 1-butylpyridinium iodide [C4py]I were developed and characterized as potential electrolytes in DSSCs. The eutectic ILs mixtures are mixed at different ratios to evaluate their thermodynamic behavior and physicochemical properties. The melting temperature of pure ILs and the mixtures were determined using differential scanning calorimetry (DSC) in the temperature range of 123.15 K to 393.15 K. It is found that eutectic mixtures were formed at the molar ratios of {0.75[C2py]I : 0.25[C2C1im]I}, {0.25[C2py]I : 0.75[C2C1im]I}, {0.50[C2py]I : 0.50[C2C1im]I}, {0.75[C4py]I : 0.25[C2C1im]I}, {0.25[C4py]I : 0.75[C2C1im]I} and {0.50[C4py]I : 0.50[C2C1im]I} with the latter forming a highly stable liquid with no apparent melting peak in the studied temperature range. To understand the formation of eutectic composition, a correlation between molecular structures and the interaction energies of the cations and anions of ILs was performed using Conductor-like Screening Model for Real Solvents (COSMO-RS). Dynamic viscosities of the binary mixtures and eutectic ILs electrolytes were evaluated in the temperature range of 283.15 K to 353.15 K with 10 K increments. The highest ionic conductivity was exhibited by the eutectic ILs electrolyte {0.50[C2C1im] I:0.50[C4py] I: I2 (50 wt%)} at 9.67 mS·cm−1. Further photovoltaic performance evaluation of fabricated DSSCs showed a power conversion of 0.51% short circuit current, JSC at 2.68 mA/cm2 and open-circuit voltage, VOC of 0.43 V demonstrating its potential for electrolyte application in DSSC.
format Thesis
author MOHD FARIDZ HILMY, NURFATHIAH IZZATY
author_sort MOHD FARIDZ HILMY, NURFATHIAH IZZATY
title Development of Eutectic Ionic Liquids as an Electrolyte in Dye-Sensitized Solar Cells (DSSCs)
title_short Development of Eutectic Ionic Liquids as an Electrolyte in Dye-Sensitized Solar Cells (DSSCs)
title_full Development of Eutectic Ionic Liquids as an Electrolyte in Dye-Sensitized Solar Cells (DSSCs)
title_fullStr Development of Eutectic Ionic Liquids as an Electrolyte in Dye-Sensitized Solar Cells (DSSCs)
title_full_unstemmed Development of Eutectic Ionic Liquids as an Electrolyte in Dye-Sensitized Solar Cells (DSSCs)
title_sort development of eutectic ionic liquids as an electrolyte in dye-sensitized solar cells (dsscs)
publishDate 2021
url http://utpedia.utp.edu.my/22782/1/NURFATHIAH%20IZZATY%20MOHD%20FARIDZ%20HILMY_18002858.pdf
http://utpedia.utp.edu.my/22782/
_version_ 1741195863485579264
score 11.62408

Similar Items