Thermo oxidative degradation behavior of jatropha curcass L. oil in the presence of antioxidant

Seed oils were used as base oil since long time ago. However their usage is limited due to its thermo oxidative and cold flow properties. Chemical modification and addition of proper additives are known to be able to improve these limitations. In this work, the effect of octadecyl 3- (3,5-di-tert-bu...

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Main Authors: Syah Lubis, A.M.H., Ariwahjoedi, B., Sudin, M., Parman, S.
Format: Article
Institution: Universiti Teknologi Petronas
Record Id / ISBN-0: utp-eprints.32724 /
Published: 2013
Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84886260368&doi=10.4028%2fwww.scientific.net%2fAMM.393.893&partnerID=40&md5=6ef1249ac99657ebd4a9998dc22fa663
http://eprints.utp.edu.my/32724/
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spelling utp-eprints.327242022-03-30T01:05:08Z Thermo oxidative degradation behavior of jatropha curcass L. oil in the presence of antioxidant Syah Lubis, A.M.H. Ariwahjoedi, B. Sudin, M. Parman, S. Seed oils were used as base oil since long time ago. However their usage is limited due to its thermo oxidative and cold flow properties. Chemical modification and addition of proper additives are known to be able to improve these limitations. In this work, the effect of octadecyl 3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate as potential hindered phenol antioxidant (HPAO) on thermo-oxidative degradation of jatropha oil was investigated. 1, 3, 5 wt of antioxidant was dissolved into jatropha oil and their thermo-oxidative behavior was studied by using thermogravimetric analysis method under oxidative environment. The addition of the HPAO was found to accelerate the occurrence of thermal degradation first onset of jatropha oil. This factor corresponds to reaction of the compound during heating that reduces the peroxides formation to a less-reactive alcohol which is more volatile, thus making the first onset temperature occurred at a lower temperature. © (2013) Trans Tech Publications, Switzerland. 2013 Article NonPeerReviewed https://www.scopus.com/inward/record.uri?eid=2-s2.0-84886260368&doi=10.4028%2fwww.scientific.net%2fAMM.393.893&partnerID=40&md5=6ef1249ac99657ebd4a9998dc22fa663 Syah Lubis, A.M.H. and Ariwahjoedi, B. and Sudin, M. and Parman, S. (2013) Thermo oxidative degradation behavior of jatropha curcass L. oil in the presence of antioxidant. Applied Mechanics and Materials, 393 . pp. 893-898. http://eprints.utp.edu.my/32724/
institution Universiti Teknologi Petronas
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description Seed oils were used as base oil since long time ago. However their usage is limited due to its thermo oxidative and cold flow properties. Chemical modification and addition of proper additives are known to be able to improve these limitations. In this work, the effect of octadecyl 3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate as potential hindered phenol antioxidant (HPAO) on thermo-oxidative degradation of jatropha oil was investigated. 1, 3, 5 wt of antioxidant was dissolved into jatropha oil and their thermo-oxidative behavior was studied by using thermogravimetric analysis method under oxidative environment. The addition of the HPAO was found to accelerate the occurrence of thermal degradation first onset of jatropha oil. This factor corresponds to reaction of the compound during heating that reduces the peroxides formation to a less-reactive alcohol which is more volatile, thus making the first onset temperature occurred at a lower temperature. © (2013) Trans Tech Publications, Switzerland.
format Article
author Syah Lubis, A.M.H.
Ariwahjoedi, B.
Sudin, M.
Parman, S.
spellingShingle Syah Lubis, A.M.H.
Ariwahjoedi, B.
Sudin, M.
Parman, S.
Thermo oxidative degradation behavior of jatropha curcass L. oil in the presence of antioxidant
author_sort Syah Lubis, A.M.H.
title Thermo oxidative degradation behavior of jatropha curcass L. oil in the presence of antioxidant
title_short Thermo oxidative degradation behavior of jatropha curcass L. oil in the presence of antioxidant
title_full Thermo oxidative degradation behavior of jatropha curcass L. oil in the presence of antioxidant
title_fullStr Thermo oxidative degradation behavior of jatropha curcass L. oil in the presence of antioxidant
title_full_unstemmed Thermo oxidative degradation behavior of jatropha curcass L. oil in the presence of antioxidant
title_sort thermo oxidative degradation behavior of jatropha curcass l. oil in the presence of antioxidant
publishDate 2013
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-84886260368&doi=10.4028%2fwww.scientific.net%2fAMM.393.893&partnerID=40&md5=6ef1249ac99657ebd4a9998dc22fa663
http://eprints.utp.edu.my/32724/
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score 11.62408